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Re: Pyro Developers Question.

From: ian@lostlabours.co.uk (IanG)


On Aug 13, 3:27 pm, Lew <lew1...@gmail.com> wrote:
Isn't there also the claim that, as development & tanning progress in
highlight areas, the emulsion physically compresses (as a result of
the tanning) thereby holding less developer? ie there is even more
moderation of highlight densities than there is via the mechanism of
developer exhaustion alone.
I haven't tested this extensively, but my limited experience leads me
to believe that, on a very sunny day, with the sun overhead, plus
areas of deep shadow, using iso 200 - 400 films, I did obtain easy to
print negatives with plenty of highlight detail.

Pyrocatechin (and Pyrogallol) work by acting on the surface of the
emulsion tanning & hardening the emulsion as the developers is used
and oxidises, particularly in the highlights. It's the basis of the
Pyrocatechin surface developers used to control high contrast lighting
as advocated by LP Clerc and Hans Windisch etc. So yes you are
correct.

The same effect is used in some Lith/Graphic arts  developers, German
formulae often used Pyrocatechin in place of Hyrdroquinone, the two
are to some extent interchangeable. Kodak also used Pyrocatechin
instead of Hydroquinone in HC110 for a while.

Ian


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