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Re: Pyro Developers Question.

From: dickburk@ix.netcom.com (Richard Knoppow)



"Lew" <lew1716@gmail.com> wrote in message
news:db44e57c-6a79-42e1-9f85-f4f839786793@c10g2000yqi.googlegroups.com...
Isn't there also the claim that, as development & tanning
progress in
highlight areas, the emulsion physically compresses (as a
result of
the tanning) thereby holding less developer? ie there is
even more
moderation of highlight densities than there is via the
mechanism of
developer exhaustion alone.
I haven't tested this extensively, but my limited
experience leads me
to believe that, on a very sunny day, with the sun
overhead, plus
areas of deep shadow, using iso 200 - 400 films, I did
obtain easy to
print negatives with plenty of highlight detail.
    I have never seen this suggested and doubt very much if
it happens. Developer penetrates by diffusion from the
surface. The "hardness" of the gelatin has little to do with
it. AFAIK, there is no such action due to differential
hardening.
    There is a differential imagewise shrinkage of the
emulsion but it probably happens as the emulsion dries. One
result of this is an acutance effect due to a difference of
index of refraction along the demarcation of high and low
density areas. It also produces a distortion of the image on
a very small scale but enough so that tanning developers are
undesirable for photo metrology purposes.


--
--
Richard Knoppow
Los Angeles, CA, USA
dickburk@ix.netcom.com





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